✦ LIBER ✦
Structure-reactivity relationships in triplet sensitized photolysis of aromatic ketone O-acyloximes
✍ Scribed by Hirochika Sakuragi; Masayuki Yoshida; Hideko Kinoshita; Kimie Utena; Katsumi Tokumaru; Masamatsu Hoshino
- Book ID
- 104245648
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- French
- Weight
- 145 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Structure-reactivity relationships in photoreactio;s are of great interest and importance. 1 Previously 0-acyloximes of aromatic ketones were shown to undergo homolytic cleavage at the N-O bond on excitation to their triplet states. 2
We now wish to report on studies designed to determine structural factors responsible for reactivity of the triplet states of aromatic ketone 0-acyloximes.
The mechanism of the triplet sensitized photolysis of the 0-acyloximes is
shown by the following kinetic scheme: