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Structure-reactivity relationships and the rate-determining step in the nucleophilic cleavage of phenyl salicylate with primary and secondary amines

✍ Scribed by Khan, M. Niyaz


Book ID
126100913
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
869 KB
Volume
48
Category
Article
ISSN
0022-3263

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Nucleophilic second-order rate constants, k n ms , for the reactions of several primary and secondary amines with ionized phenyl salicylate (PS Ϫ ) show a nonlinear decrease with the increase in the content of CH 3 CN from 2 to Յ50% v/v in mixed aqueous solvent. The values of k n ms remain almost un