The reactions of a series of secondary alicyclic amines with 4-methylphenyl and 4-methoxyphenyl chloroformates are subjected to a kinetic investigation in water, at 25.0ЊC, ionic strength 0.2 M (KCl). Under amine excess, pseudo-first-order rate coefficients (k obs ) are found for all reactions. Plot
Structure-Reactivity correlations in the addition of water to aromatic substrates
✍ Scribed by Rita H. De Rossi; Alicia Veglia
- Publisher
- John Wiley and Sons
- Year
- 1985
- Tongue
- English
- Weight
- 482 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0538-8066
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The kinetics of addition of a number of ortho-, meta-, and para-substituted benzylamines to benzylidenemalononitrile (BMN) in acetonitrile have been studied. The reaction is first-order with respect to BMN. The order with respect to the amine is more than one. It has been shown that the reaction fol
The kinetics o f addition of a number of ortho-. rneta-, and para-substituted benzylarnines to ethyl a-cyanocinnamate [ECC) in acetonitrile have been studied. T h e reaction is First-order with respect to the amine and ECC. The rates of reaction of rneta-and para-substituted benzylamines showed exce