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Structure of (ZrO2)x(SiO2)1-x xerogels (x=0.1, 0.2, 0.3 and 0.4) from FTIR, 29Si and 17O MAS NMR and EXAFS

โœ Scribed by Pickup, David M.; Mountjoy, Gavin; Wallidge, Graham W.; Newport, Robert J.; Smith, Mark E.


Book ID
111689004
Publisher
Royal Society of Chemistry
Year
1999
Tongue
English
Weight
168 KB
Volume
1
Category
Article
ISSN
1463-9076

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A 5-layer mixed valence oxide, \(\mathrm{BaVO}_{2.8}\), has been synthesized by reducing \(\mathrm{Ba}_{2} \mathrm{~V}_{2} \mathrm{O}_{7}\) in high purity hydrogen gas at \(1350^{\circ} \mathrm{C}\). \(\mathrm{BaVO}_{2.9}\) has been obtained by room temperature oxidation of \(\mathrm{BaVO}_{2.8}\) i