Gas-Phase Reactions of M+ and [CpM]+ (M
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Dr. Asgeir Bjarnason; Prof. Dr. Ingvar Arnason
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Article
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1992
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John Wiley and Sons
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English
β 276 KB
π 2 views
When starting with racemates, OY,,,,, = -l)i([j" + I ) , while for a sample ofcomposition (tl, I ) OY,,, = j([jd + 1) -2(/k/41'2)!tl(/1 -1). The optical yield can be related to the thermodynamic chirdl recognition. AAG = -RT1nl.i. as /j = [(I + OY)/(l -OY]' when d = l = I = 0.5 (0 s OY < 1 ). [12]