Four pectic polysaccharides (AR-2IIa-IId) with anti-complementary activity have been isolated from a hot-water extract of the root of Angelica acutiloba Kitagawa. Each of these polysaccharides contained a large proportion of GalA together with neutral sugars consisting mainly of Rha, Ara, and Gal. D
Structure of the neutral carbohydrate side-chains in anti-complementary acidic polysaccharides from the root of Angelica acutiloba kitagawa
β Scribed by Hiroaki Kiyohara; Haruki Yamada
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 546 KB
- Volume
- 187
- Category
- Article
- ISSN
- 0008-6215
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β¦ Synopsis
The endo-a-(1--3-4)-polygalacturonase-resistant regions (PG-la-1c) from three anti-complementary acidic polysaccharides (AR-211a-He), isolated from the root of Angelica acutiloba Kitagawa, were subjected to base-catalysed ,S-elimination in the presence of sodium borodeuteride . Each PG-l gave a neutral (N) and an acidic fraction (A), but each fraction A was resistant to further 1/33-elimination . Each fraction N consisted of Ara, Gal, and Rha, whereas each fraction A contained a large proportion of GaIA and small proportions of neutral sugars . Methylation and g .l .c.-m .s .
π SIMILAR VOLUMES
One of the anti-complementary pectic polysaccharides (AR-2IIa) isolated from the root of Angelica acutiloba Kitagawa gives the "ramified" region (PG-la, rhamnogalacturonail with neutral side-chains) in addition to oligogalacturonides on digestion with endo-a-o-(l-+4)-polygalacturonase. When the neu