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Structure of the methyl radical

✍ Scribed by Cole, T.; Pritchard, H.O.; Davidson, N.R.; McConnell, H.M.

Book ID
121392096
Publisher
Taylor and Francis Group
Year
1958
Tongue
English
Weight
244 KB
Volume
1
Category
Article
ISSN
0026-8976

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## Abstract The structure and reactivity of the cysteine methyl ester radical cation, CysOMe^.+^, have been examined in the gas phase using a combination of experiment and density functional theory (DFT) calculations. CysOMe^.+^ undergoes rapid ion–molecule reactions with dimethyl disulfide, allyl