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Structure of the bis[bis(diphenylphosphino)methane]digold(I) cation in [Au2(dppm)2](BF4)2

✍ Scribed by Porter, L. C. ;Khan, Md. N. I. ;King, C. ;Fackler Jnr, J. P.


Book ID
114506107
Publisher
International Union of Crystallography
Year
1989
Tongue
English
Weight
311 KB
Volume
45
Category
Article
ISSN
0108-2701

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Bis[ΞΌ-bis(diphenylphosphino)methane-ΞΊ2P:
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In the centrosymmetric dicationic cyclic title compound [Au 2 (C 25 H 22 P 2 ) 2 ](NO 3 ) 2 Á2CD 3 OD, an aurophilic interaction with a distance of 3.0245 (3) A ˚is found between the lineardicoordinated Au I centres. The perdeuteromethanol solvent molecules are linked to the nitrate anions via hydro