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Structure of some homo- and heteroassociates of methanol with trimethylamine and quantum-chemical substantiation of the role of hydrogen bonding in the mechanism of urethane-formation reactions

โœ Scribed by E. A. Chernova; R. P. Tiger; O. G. Tarakanov


Publisher
SP MAIK Nauka/Interperiodica
Year
1986
Tongue
English
Weight
499 KB
Volume
27
Category
Article
ISSN
0022-4766

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Formation of semiquinone radical in the
โœ Ravi Joshi; Tapan K. Ghanty; Tulsi Mukherjee ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 638 KB

Embelin, 2,5-dihydroxy-3-undecyl-1,4-benzoquinone, has two intra-molecular hydrogen bonds between the quinone and hydroquinone groups present on the same ring. Therefore, it is expected to produce semiquinone radical in the oxidation as well reduction reactions. To investigate this aspect, kinetics