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Structure of polypropene and poly(ethylene-co-propene) produced with an alumina-supported CpTiCl3/common alkylaluminium catalyst system

✍ Scribed by Kazuo Soga; Toshiya Uozumi; Masayoshi Saito; Takeshi Shiono

Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
412 KB
Volume
195
Category
Article
ISSN
1022-1352

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✦ Synopsis

Abstract

Both propene polymerization and ethylene/propene copolymerization were conducted with an Al~2~O~3~‐supported CpTiCl~3~ (Cp: cyclopentadienyl) catalyst using a common alkylaluminium as cocatalyst. The catalyst system gave atactic polypropene with frequently inverted propene units which are randomly distributed over the polymer chain. The structure of poly(ethylene‐co‐propene) produced with the catalyst system was found to be very different from that obtained with ordinary titanium based catalysts.

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