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Structure of Polyelectrolytes in Solution: A Monte Carlo Study

✍ Scribed by Schäfer, Heiko; Seidel, Christian


Book ID
125922797
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
235 KB
Volume
30
Category
Article
ISSN
0024-9297

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The lnlluence of the polygon charge densely on the osmollc behawor of hncar polyelectrolyies IS stu&ed by the Monte Carlo method and by the mticd Poisson-Boltzmann equation. The polpon IS assumed to be either a uniformly or dwxetely charged cyhnder placed along the axis of tbe cyhndncal cd conmmmg o

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## SYNOPSIS The discontinuous transition between dense and dilute phases in polyelectrolyte gels is observed in Bond-Fluctuation Method Monte Carlo simulations of gels. The transition is driven by the competition between local attractive interactions of a poor-quality solvent and global repulsive