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Structure of Nα-acetyl-N-methyl-l-tryptophanamide

✍ Scribed by Souhassou, M. ;Aubry, A. ;Lecomte, C. ;Marraud, M.

Book ID
114506759
Publisher
International Union of Crystallography
Year
1990
Tongue
English
Weight
313 KB
Volume
46
Category
Article
ISSN
0108-2701

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📜 SIMILAR VOLUMES

Flash photolysis of N-acetyl-L-tryptopha
Flash photolysis of N-acetyl-L-tryptophanamide; acid-base equilibrium of the radical transients
✍ R.F. Evans; C.A. Ghiron; W.A. Volkert; R.R. Kuntz 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 306 KB

The transient with a A,, at 570 nm observed in the flash photolysis of Nacetyl-L-tryptophanamide is confirmed to be the positive radical This species 1s in rapid equilibrium with Its deprotonated form (hmax = 5 10 nm) with a pK of 4.3.

Flash photolysis of N-acetyl-L-tryptopha
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✍ R.F. Evans; C.A. Ghiron; R.R. Kuntz; W.A. Volkert 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 416 KB

Proton quenching of fluorescence, radical and electron production in the flash photorysis of N-acetyl-L-tryptophanamide indicates these processes originate from a common state. An indole photolysis model consistent with these and carlier observations is suggested.