The title heterocycles rearrange into a mixture of diastereoisomeric hexahydro-l(ZH)-pentalenone derivatives, which undergo nucleophilic eliminative ring fission by methanol to give I-amino-2-nitroalkylated cyclopentancarboxylic esters. The X-ray structure determination of hexahydro-2-methyl-2-nitro
β¦ LIBER β¦
Structure of N-substituted 1,2-oxazines. II. Bicyclic bridged derivatives
β Scribed by Tinant, B. ;Declercq, J. P.
- Book ID
- 114508023
- Publisher
- International Union of Crystallography
- Year
- 1991
- Tongue
- English
- Weight
- 434 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0108-2701
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## Abstract The addition of dichlorocarbene (generated by the interaction of sodium methoxide and ethyl trichloroacetate) to bicyclo[3.2.1]octβ2βene, its 3βchloro and __exo__β3,4βdichloro derivatives gives the __exo__ 1 : 1 adducts in yields of 94, 89 and 48%. By suitable chemical reactions of thes