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Structure of methyl 6-deoxy-α-d-idopyranoside

✍ Scribed by Robert M. Giuliano; Robert F. Bryan; Paul Hartley; Seth Peckler; Moses K. Woode

Book ID: 107725859
Publisher: Elsevier Science
Year: 1989
Tongue: English
Weight: 763 KB
Volume: 191
Category: Article
ISSN: 0008-6215
DOI: 10.1016/0008-6215(89)85041-4

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## Abstract Methyl 2‐__O__‐benzyl‐6‐deoxy‐3‐__C__‐methyl‐α‐D‐mannopyranoside (2) was synthesized in ten steps by starting from the readily available methyl 2,3‐anhydro‐4,6‐__O__‐benzylidene‐α‐D‐allo‐pyranoside (3). The key step was the stereoselective __cis__‐hydroxylation (cat. osmium(VIII) oxide)