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Structure of Hydrocarbons Synthesized by the Alga BotryococcusIsolated from Lake Shira

✍ Scribed by N. O. Zhila; G. S. Kalacheva; T. G. Volova; A. G. Degermendzhi

Book ID
110386677
Publisher
Springer
Year
2001
Tongue
English
Weight
55 KB
Volume
378
Category
Article
ISSN
0012-4966

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Giffordene ( = (22,42,6E,82)-2,4,6,8-~ndecatetraene; 9f) and five stereoisomers are new C , ,HI, hydrocarbons from the marine brown alga G$fordia mitchellae. Their synthesis is based on non-stereoselective Wittig reactions of (E)-2-alkenals with appropriate acetylenic phosphoranes and subsequent chr