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Structure of ethylene sulphide crystallites in block copolymers

✍ Scribed by D.E. Eaves; A. Stokes


Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
322 KB
Volume
11
Category
Article
ISSN
0014-3057

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✦ Synopsis


Block copolymers, having the configuration ethylene sulphide-isoprene-styrene or ethylene sulphide-isoprene ethylene sulphide, have been characterized to define the structure of the ethylene sulphide moiety. It is concluded that ethylene sulphide-isoprene-styrene block copolymers exist in solution and in bulk (above the styrene softening point)as radial aggregates held together by polyethylene sulphide crystallites. During polymerization, these crystallites are formed with a linear extended chain morphology which is retained in bulk in ethylene sulphide-isoprene styrene copolymers: in the copolymers which require processing above the melting point of the ethylene sulphide crystallites, the linear morphology is destroyed during moulding.


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