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Structure of electrified interfaces

Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
135 KB
Volume
6
Category
Article
ISSN
1040-0397

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πŸ“œ SIMILAR VOLUMES

Field theoretic approach of electrified
Field theoretic approach of electrified interfaces
✍ J. Stafiej; M. Dymitrowska; J.P. Badiali πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 743 KB

We describe the primitive model of an electrochemical interfac: by using a free energy functional of the Landau type. The relevant variables are assumed to be the charge and total ion density and the Coulomb interaction is explicitly taken into account. Explicit results are obtained in a mean field

Quantum chemical models for electrified
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Quantum chemical models for a charged interface are discussed. A new approach based on the renormalization of the density matrix is proposed in order to describe a continual surface charge distribution. Ab initio quantum chemical calculations were carried out for a small mercury cluster. The adsorpt