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Structure of di(tert-butyl)bis(N,N-dimethyldithiocarbamato)tin(IV)

✍ Scribed by Kim, K. ;Ibers, J. A. ;Jung, O. S. ;Sohn, Y. S.


Book ID
114504373
Publisher
International Union of Crystallography
Year
1987
Tongue
English
Weight
342 KB
Volume
43
Category
Article
ISSN
0108-2701

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In the title compound, [Sn(C 4 H 9 ) 2 (C 3 H 6 NS 2 )Cl], the Sn IV atom has a distorted trigonal bipyramidal geometry that is defined by Cl, two S and two C atoms. The dithiocarbamate chelates to the Sn atom in an anisobidentate manner, and the double-bonded S atom occupies one of the two axial si