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Structure of dimers of NAD+ and of N-benzyl nicotinamide chloride.

✍ Scribed by Jean-Francois Biellmann; Claude Lapinte

Book ID
104237127
Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
195 KB
Volume
19
Category
Article
ISSN
0040-4039

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✦ Synopsis

Dimers of NAD+ (nicotinamide adenine dinucleotide) and of model compounds have been obtained either by reduction with metals (1) or by electrochemical methods (2, 3, 4). The structures of these dimers which most likely have a 2-2', 4-4' or 6-6' bond between the dihydropyridine rings (5, 6, 7) have never been quite well established.

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In aqueous media the one-electron reduction of the title a structure for these conformers and their stability has been studied. Two conformers are unstable, yielding the third compounds on a mercury pool generally gives rise to three dimers, which are distinguishable by HPL chromatography. conformer