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Structure of di-μ-chloro-tetrachlorobis(tetrahydrofuran)-[μ-(dimethyl sulfide)]-diniobium(Nb–Nb), [Nb2Cl6(C4H8O)2(C2H6S)], and di-μ-chloro-tetrachlorobis(tetrahydrofuran)-[μ-(dimethyl sulfide)]-ditantalum(Ta–Ta), [Ta2Cl6(C4H8O)2(C2H6S)]

✍ Scribed by Cotton, F. A. ;Duraj, S. A. ;Roth, W. J.


Book ID
114502930
Publisher
International Union of Crystallography
Year
1985
Tongue
English
Weight
420 KB
Volume
41
Category
Article
ISSN
0108-2701

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Synthesis, Structural Characterisation a
✍ Antonio Antiñolo; Iván Dorado; Mariano Fajardo; Andrés Garcés; Isabel López-Sol 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 254 KB 👁 1 views

## Abstract The preparation of a family of dinuclear monocyclopentadienyl imidoniobium and ‐tantalum complexes was achieved by two different synthetic routes. The diimido complexes [{M(Cp′)Cl~2~}~2~(μ‐1,__i__‐NC~6~H~4~N)] [Cp′ = η^5^‐C~5~H~4~SiMe~3~, M = Nb, __i__ = 4 (1); Cp′ = η^5^‐C~5~H~4~SiMe~3