Structure of densified vitreous silica: Silicon and oxygen XANES spectra and multiple scattering calculations
β Scribed by I. Davoli; E. Paris; S. Stizza; M. Benfatto; M. Fanfoni; A. Gargano; A. Bianconi; F. Seifert
- Book ID
- 104661491
- Publisher
- Springer-Verlag
- Year
- 1992
- Tongue
- English
- Weight
- 549 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0342-1791
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β¦ Synopsis
The decrease of the mean Si-O-Si angle in vitreous silica upon densification from 2.20 to 2.36 gcm -3 has been followed by oxygen and silicon K-edge XANES spectroscopy. Multiple scattering calculations using clusters of two shells around the oxygen and silicon atoms, respectively, are in good agreement with experimental absorption spectra and confirm mean Si-O-Si angles between 130 and 144 ~ for these samples, and a decrease of the mean angle with densification. The experimental spectra also exhibit features due to scattering at outer (>2) shells around the photoabsorbers.
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