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Structure of Cobalt Complexes with Salicylideneanilines

✍ Scribed by WEST, B. O.

Book ID
109577603
Publisher
Nature Publishing Group
Year
1954
Tongue
English
Weight
292 KB
Volume
173
Category
Article
ISSN
0028-0836

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The phosphoraneiminato complexes [MnBr(NPEt 3 )] 4 (1) and [M 4 Br 5 {NP(NMe 2 ) 3 } 3 ] with M = Mn (2) and M = Co (3) are prepared by melting reactions from the anhydrous metal dibromides with the silylated phosphaneimines Me 3 SiNPR 3 (R = Et, NMe 2 ) in the presence of potassium fluoride. All co