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Structure of bis(dimethylphenylphosphine)(ethylene)(carbonyl)dichlororuthenium(II), RuCl2(CO)(C2H4)(P(CH3)2(C6H5))2, a six-coordinate d6 complex containing ethylene as a ligand

✍ Scribed by Brown, Leo D.; Barnard, C. F. J.; Daniels, J. A.; Mawby, R. J.; Ibers, James A.


Book ID
126245637
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
509 KB
Volume
17
Category
Article
ISSN
0020-1669

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The tetrakis(phosphane oxide) C 6 H 2 {CH 2 P(O)Ph 2 } 4 -1,2,4,5 (5), has been prepared in high yield from the Arbuzov reaction of C 6 H 2 (CH 2 Br) 4 -1,2,4,5 (4), with excess (7 equiv.) of Ph 2 POEt. Subsequent reduction of 5 with HSiCl 3 (12 equiv.) in C 6 H 4 Cl 2 -1,2 afforded the new tetrapho