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Structure of bis(4-chlorophenolato)[hydrotris(3,5-dimethyl-1-pyrazolyl)borato]oxomolybdenum(V)

โœ Scribed by Chang, C. S. J. ;Pecci, T. J. ;Carducci, M. D. ;Enemark, J. H.


Book ID
114509025
Publisher
International Union of Crystallography
Year
1992
Tongue
English
Weight
228 KB
Volume
48
Category
Article
ISSN
0108-2701

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An improved synthesis of 3,5-bis(trifluoromethyl)pyrazole (1) is described. This compound was used for the high-yield syntheses of the tris(pyrazoly1)borates Nd [HB(3,,-pz),1 (2a) and the corresponding potassium salt, 2b, starting from 1 and NaBH, and KBH,, respectively. A convenient route to the co