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Structure of Ba2Cu3 S2[VS4], a new alkaline-earth copper thiovanadate

✍ Scribed by C. Mujica; C. Ulloa; J. Llanos; K. Peters; E.-M. Peters; H.G. von Schnering


Book ID
117623581
Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
559 KB
Volume
255
Category
Article
ISSN
0925-8388

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Novel Alkaline Earth Metal Chalcogenobor
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Systematic studies on quaternary thio-and selenoborates containing heavier alkaline earth metal cations led to the two new isotypic crystalline phases Sr 4.2 Ba 2.8 (BS 3 ) 4 S and Ba 7 (BSe 3 ) 4 Se. Both compounds consist of trigonal-planar BQ 3 (Q = S, Se) units, isolated Q 2Β± anions and the corr