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Structure of a Phosphorus-Nitrogen Ylide Having Two-fold Coordinated Phosphorus

✍ Scribed by Dr. Siegfried Pohl


Publisher
John Wiley and Sons
Year
1976
Tongue
English
Weight
228 KB
Volume
15
Category
Article
ISSN
0044-8249

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Arsadiphosphabenzenes 1,l-Bis[(diphenylphosphanyl)methyl]ethene (3) reacts with PC13 or AsCl, in the presence of SnC12 as a reducing agent to form cationic heterocycles in which the two newly generated phosphonium centers are bridged by two-coordinate, negatively charged phosphorus (4a) or arsenic (