## Abstract In addition to the already known 3β,6α‐dihydroxy‐5α‐pregn‐9(11)‐en‐20‐one (**1**), 3β,6α,20ξ‐trihydroxy‐5α‐cholest‐9(11)‐en‐23‐one (**2**), 3β,6α,20ξ‐trihydroxy‐24ξ‐methyl‐5α‐cholest‐9(11)‐en‐23‐one (**3**) [isolated in the form of the diacetates **1**′, **2**′, and **3**′ from the enzy
Structure of a novel type steroid glycoside, 18-norspirostanol oligoglycoside
✍ Scribed by T. Nohara; A. Nakano; K. Miyahara; T. Komori; T. Kawasaki
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- French
- Weight
- 223 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Previously it was reported 1) that eight kinds of glycosides of pennogenin, kryptogenin and their related sapogenins were isolated from the fresh rhizomes of Trillium kamtschaticum PG.
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A nom2 steroidal glycoside has been isolated from the starfish Protoreaster nodosus. The structure includes a 3B,5a,6B,8B,lScr,24S-hexahydroxysteroidal moiety and a sugar moiety [2-0-methyl-B-D-xylopyranosyl-(1 + 21-a-L-arabinofuranosyZ]which is glycosidicaZZy attached at C-24 of the aglycone.
Some years ago, Tomko et al. (I) isolated a secondary alkaloid, veralkamine, from Veratrum album ssp. lobelianum (Bernh.) Suessenguth. In alteration of a formerly proposed provisional constitution (2) its complete structure has been established by recent chemical and physical reinvestigations includ
NEARLY twenty years ago, Marker et al. (1) suggested that the true naturally occurring steroidal saponins synthesized by plants might have an open side chain moiety in which ring closure to the spiroketal structure encountered in the corresponding sapogenins is prevented by conjugation of the hydrox