Syntheses of deoxyhexoses from diastereo
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Tomasz Bauer
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Article
📅
1997
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Elsevier Science
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French
⚖ 269 KB
Syntheses of deoxyhexoses are presented. The concept is based on the functionalization of enantiomerically pure 6-hydroxymethyl-2-methoxy-5,6-dihydro-2H-pyran, which is easily synthesized by asymmetric hetero-Diels-Alder reaction. Methyl 4,6-dideoxy-a-o-arabino-hexopyranoside, methyl a-o-chalcoside