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Structure of a hetero-Diels–Alder adduct

✍ Scribed by Antel, J. ;Sheldrick, G. M. ;Brumby, T. ;Tietze, L. F.


Book ID
114505888
Publisher
International Union of Crystallography
Year
1989
Tongue
English
Weight
227 KB
Volume
45
Category
Article
ISSN
0108-2701

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Syntheses of deoxyhexoses from diastereo
✍ Tomasz Bauer 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 269 KB

Syntheses of deoxyhexoses are presented. The concept is based on the functionalization of enantiomerically pure 6-hydroxymethyl-2-methoxy-5,6-dihydro-2H-pyran, which is easily synthesized by asymmetric hetero-Diels-Alder reaction. Methyl 4,6-dideoxy-a-o-arabino-hexopyranoside, methyl a-o-chalcoside