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Structure of a five-coordinate copper(II) complex: (2,2'-bipyridine)[4,4,4-trifluoro-1-(2-thienyl)butane-1,3-dionato-O][4,4,4-trifluoro-1-(2-thienyl)butane-1,3-dionato-O,O']copper(II)

✍ Scribed by Xu, Z. ;Gou, S. H. ;You, X. Z. ;Liu, S. X. ;Lin, C. C. ;Yu, Y. P. ;Zhu, D. L.


Book ID
114507616
Publisher
International Union of Crystallography
Year
1991
Tongue
English
Weight
353 KB
Volume
47
Category
Article
ISSN
0108-2701

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In the centrosymmetric title compound, [Cu(C 10 H 5 F 3- NO 4 ) 2 (C 5 H 5 N) 2 ], the Cu II atom is hexacoordinate and lies in a square plane formed by four O atoms. Two pyridine molecules complete the coordination in trans positions. In the crystal structure there are intramolecular C-HÁ Á ÁF and