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Structure of a chelating phosphine rhenium(I) complex: fac-tricarbonylchloro[1,1,1-tris(diphenylphosphinemethyl)ethane]rhenium(I)

✍ Scribed by Lin, S. C. ;Cheng, C. P. ;Lee, T. Y. ;Lee, T. J. ;Peng, S. M.

Book ID: 114503363
Publisher: International Union of Crystallography
Year: 1986
Tongue: English
Weight: 449 KB
Volume: 42
Category: Article
ISSN: 0108-2701
DOI: 10.1107/s0108270186090765

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## Abstract Reactions of copper(I) halides with 1,1,1‐tris(diphenylphosphanylmethyl)ethane (triphos) in 1:1 molar ratio afforded mononuclear complexes of the type [CuX(triphos)] which on further treatment with one equivalent of the potassium thiolate salt of a heterocyclic thione gave rise to the f