In the title compound, C 12 H 18 O 5 , the ring has a chair conformation, with endocyclic torsion angle magnitudes in the range 47.7 (3)-66.7 (2) . The OH group donates an intermolecular hydrogen bond to a C O group with an OÁ Á ÁO distance of 2.791 (3) A ˚, forming chains. organic papers o2662 Burt
✦ LIBER ✦
Structure of (5RS,6RS)-1,5-diacetyl-6-benzoxymethyl-2-hydroxy-4-methyl-1,3-cyclohexadiene
✍ Scribed by Moreno, E. ;Perez, S. ;López-Castro, A. ;Márquez, R.
- Book ID
- 114504825
- Publisher
- International Union of Crystallography
- Year
- 1987
- Tongue
- English
- Weight
- 328 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0108-2701
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The polysubstituted piperidine enol ring in the title compound, C~29~H~31~NO~3~S, adopts a twisted half-chair conformation. The crystal structure is stabilized by van der Waals and weak C—H...π interactions. An intramolecular O—H...O interaction generates an __S__(6) graph-set motif.