Structure of 3-(4-bromophenyl)-5-n-butylglutaramic acid
✍ Scribed by García-Granda, S. ;Beurskens, P. T. ;Moers, F. G. ;Chakraborty, D. K. ;Maity, S. ;Talapatra, S. K.
- Book ID
- 114506503
- Publisher
- International Union of Crystallography
- Year
- 1989
- Tongue
- English
- Weight
- 339 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0108-2701
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📜 SIMILAR VOLUMES
Molecules of the title compound, C 24 H 21 BrN 2 , are linked into chains by a single CÐHÁ Á Á%(arene) hydrogen bond, but CÐ HÁ Á ÁN hydrogen bonds and aromatic %±% stacking interactions are absent.
The title compound, C~17~H~13~BrO~3~S, was prepared by alkaline hydrolysis of ethyl 2-[5-(4-bromophenyl)-3-methylsulfanyl-1-benzofuran-2-yl]acetate. There are two symmetry-independent molecules in the asymmetric unit. The 4-bromophenyl rings are rotated out of the benzofuran planes, with dihedral an
The solid-state structure of the title compound, C 16 H 13 BrO 2 , demonstrates an E configuration about the central C C bond. Symmetry-related molecules are linked by O-HÁ Á ÁO hydrogen bonds [OÁ Á ÁO = 2.617 (3) A ˚], forming centrosymmetric carboxylic acid dimers.