Structure of (1,10-phenanthroline)salicylaldehydatocopper(II) perchlorate
β Scribed by Garland, M. T. ;Grandjean, D. ;Spodine, E.
- Book ID
- 114504536
- Publisher
- International Union of Crystallography
- Year
- 1987
- Tongue
- English
- Weight
- 340 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0108-2701
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π SIMILAR VOLUMES
Single-crystal X-ray study T = 294 K Mean (C-C) = 0.005 A R factor = 0.053 wR factor = 0.139 Data-to-parameter ratio = 12.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title complex, [Cu(C 12 H 8 N 2 ) 2 (CH 3 CN)](ClO 4 ) 2 , the five-coordinate Cu II ion has a distorted square-pyramidal coordination geometry composed of five N atoms, four from two bidentate chelating phenanthroline ligands and one from acetonitrile. The acetonitrile molecule and the Cu at