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Structure of 1-tris(trimethylsilyl)silyl-3,4,5,6-tetrakis(trimethylsilyl)cyclohex-1-ene

✍ Scribed by Dhananjay B. Puranik; Mark J. Fink


Publisher
Springer
Year
1994
Tongue
English
Weight
441 KB
Volume
24
Category
Article
ISSN
1572-8854

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The Reaction of Transient 1,1-Bis(trimet
✍ Katrin Sternberg; Helmut Reinke; Hartmut Oehme πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 German βš– 170 KB πŸ‘ 2 views

Tris(trimethylsilyl)silyllithium (3) reacted with aldehydes and ketones (molar ratio 2 : 1) according to a modified Peterson mechanism under formation of transient silenes, which were immediately trapped by excess 3 to give the organolithium derivatives (Me 3 Si) 3 SiSi(SiMe 3 ) 2 C(Li) Ε”1 R 2 (7).