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Structure of 1-exo-Phenylbicyclo[2.1.0]pentane-5-carboxylic acid by X-Ray Analysis

✍ Scribed by Gérald Bernardinelli; Jean-Jacques Combremont; Raymond Gerdil

Publisher
John Wiley and Sons
Year
1976
Tongue
German
Weight
351 KB
Volume
59
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

The title compound (C~12~H~12~O~2~) crystallizes in the monoclinic space group __P__2~1~/c. The structure was solved by direct methods, and the positions of all the hydrogen atoms were obtained from a difference synthesis. The final Rω was 0.04. Current MO theories of the interaction of unsaturated groups with small ring systems are consistent with the bond length variations encountered in the present substituted bicyclo[2.1.0]pentane skeleton with respect to the unsubstituted hydrocarbon.

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