Structure formation peculiarities of complex sulfides with a short period and symmetry mirror planes

Structure and Highly Stereoselective For

Structure and Highly Stereoselective Formation of 1:2 Metal-to-Ligand complexes with triamine 2,6-bis(pyrolidin-2-yl)pyridine. meso-[2,6-bis(pyrrolidin-2yl)pyridine]nickel(II) (meso-[Ni(bpp)2]2+), a Metal Complex with S4 Symmetry

✍ Klaus Bernauer; François Gretillat; Helen Stoeckli-Evans; Ruth Warmuth 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 German ⚖ 618 KB

The X-Ray structures of the 1:l copper(I1) complexes with racemic and optically active (+)-(R,R)-(2,6bis(pyrro1idin-2-y1)pyridine ((+)-bpp; (+)-I) were determined. Whereas the perchlorate 1 of the racemic complex contains the monomeric units with perfect C, symmetry, the sulfate of the optically act