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Structure formation in solutions of cellulose in n-methylmorpholine n-oxide and during its precipitation

โœ Scribed by S. I. Banduryan; M. M. Iovleva; Yu. Ya. Belousov; N. A. Ivanova


Publisher
Springer US
Year
1985
Tongue
English
Weight
453 KB
Volume
16
Category
Article
ISSN
0015-0541

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On the conformation of the cellulose sol
โœ T. Rosenau; A. Hofinger; A. Potthast; P. Kosma ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 150 KB

The N-oxide group of the cellulose solvent N-methylmorpholine-N-oxide showed a strong preference for the axial position compared with N-methyl as determined by NMR experiments and computational studies. In solvents with negligible solvent -solute interaction, about 95% of the NMMO molecules obtained