Structure elucidation of an unprecedented alkaloid and a new limonoid from Xylocarpus granatum
β Scribed by Jianxin Cui; Jie Ouyang; Zhiwei Deng; Wenhan Lin
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 142 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0749-1581
- DOI
- 10.1002/mrc.2273
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β¦ Synopsis
Abstract
An unprecedented new limonoidβbased alkaloid, granatoine (1), and a new phragmalin, xylocarpin L (2), along with xyloccensin Y were isolated as minor components from the fruits of the Chinese mangrove plant Xylocarpus granatum. Their structures were elucidated by extensive spectroscopic data (1D and 2D NMR) analysis. A possible biogenetic pathway for granatoine was also depicted. Copyright Β© 2008 John Wiley & Sons, Ltd.
π SIMILAR VOLUMES
## Abstract Xylocarpins A and B, two new mexicanolides with a tiglate group at Cβ3, have been identified in the mixture using NMR spectroscopy. Both compounds were isolated in the mixture from the seeds of a Chinese mangrove __Xylocarpus granatum__. The first complete assignments of ^1^H and ^13^C
## Abstract Godavarin K (**1**), a new limonoid with an oxygen bridge between C(1) and C(29), was obtained from seeds of an Indian mangrove, __Xylocarpus moluccensis__, together with a known tetranortriterpene, 6βde(acetyloxy)β7βdeacetylchisocheton compound E (=(5__Ξ±__,7__Ξ±__,13__Ξ±__,17__Ξ±__)β7βhyd