𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Structure elucidation and complete NMR spectral assignments of two new sesquiterpene lactone xylosides from Lactuca triangulata

✍ Scribed by Klaudia Michalska; Marek Żylewski; Wanda Kisiel


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
89 KB
Volume
46
Category
Article
ISSN
0749-1581

No coin nor oath required. For personal study only.

✦ Synopsis


Abstract

Two new sesquiterpene lactone xylosides, derivatives of the guaianolides 9α‐hydroxyleucodin and 9α‐hydroxy‐11,13‐dehydroleucodin, were isolated from roots of Lactuca triangulata. Their structures were established on the basis of ^1^H and ^13^C NMR spectra, 2D NMR (HMQC, HMBC, COSY, NOESY) techniques and comparison with the literature data. The compounds represent the first example of sesquiterpene lactone xylosides. Copyright © 2008 John Wiley & Sons, Ltd.


📜 SIMILAR VOLUMES


Complete NMR spectral assignments of two
✍ Klaudia Michalska; Edward Szneler; Wanda Kisiel 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 142 KB

Complete ^1^H and ^13^C NMR signal assignments of two lactucin‐type sesquiterpene lactone glycosides, derivatives of 11β,13‐dihydrolactucin, isolated from roots of __Picris conyzoides__, were achieved by one‐ and two‐dimensional NMR experiments, allowing the correction of previously published data f

Structure elucidation and complete NMR s
✍ Guan Ye; Jing-jing Fang; Ming-song Fan; Cheng-gang Huang 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 90 KB 👁 1 views

## Abstract A novel sesquiterpene glycoside was isolated from the whole plant of __Ixeris sonchifolia.__ The structure was established as 1(10)__E__‐4__Z__‐3α‐hydroxy‐germacra‐1(10),4,11(13)‐trien‐6, 12‐olide‐14‐__O__‐β‐D‐glucopyranoside (1) on the basis of spectroscopic techniques and chemical ana

Structure elucidation and complete NMR s
✍ Hai-Ping Jiang; Ying-Kun Qiu; Da-Ren Cheng; Ting-Guo Kang; De-Qiang Dou 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 153 KB 👁 1 views

## Abstract Two new saponins were isolated from leaves of __Panax quinquefolium__ and their structures were elucidated as 3β, 12β, 20__S__‐trihydroxy‐25‐methoxydammar‐23‐ene 3‐__O__‐{[β‐D‐glucopyranosyl(1→2)‐β‐D‐glucopyranosyl]‐20‐__O__‐[α‐L‐arabinopyranosyl(1→6)]‐β‐D‐glucopyranoside (1) and 3β, 20

Structure elucidation and complete NMR s
✍ De-Qiang Dou; Fang Tian; Ying-Kun Qiu; Ting-Guo Kang; Feng Dong 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 117 KB 👁 1 views

## Abstract Four new diterpenoids, named smaditerpenic acid A–D, together with five known compounds, were isolated from the H~2~O extract of the leaves of __Smallantus sonchifolius__ (yacon) cultivated in Liaoning, China and their structures were elucidated on the basis of one‐ and two‐dimensional

Structure elucidation and complete NMR s
✍ Yuanyuan Lu; Jianguang Luo; Lingyi Kong 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 177 KB 👁 1 views

## Abstract Two new furostanol glycosides, torvosides O (1) and P (2), were isolated from leaves of __Solanum torvum__. Their structures were completely and unambiguously assigned by one‐ and two‐dimensional NMR techniques (^1^H NMR, ^13^C NMR, TOCSY, HSQC, ROESY and HMBC), ESI‐MS spectrometry and

Structure elucidation and complete NMR s
✍ Changhong Huo; Dongge An; Bin Wang; Yuying Zhao; Wenhan Lin 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 98 KB

## Abstract A new benzoxazolinone glucoside, 4‐__O__‐β‐D‐glucopyranosyl‐benzoxazolin‐2(3__H__)‐one, was isolated from __Acanthus ilicifolius__, a medicinal plant from south China. The complete ^1^H and ^13^C NMR assignments of the compound were carried out by using DEPT, HMBC, HMQC, NOESY and ^1^H