Complete ^1^H and ^13^C NMR signal assignments of two lactucin‐type sesquiterpene lactone glycosides, derivatives of 11β,13‐dihydrolactucin, isolated from roots of __Picris conyzoides__, were achieved by one‐ and two‐dimensional NMR experiments, allowing the correction of previously published data f
Structure elucidation and complete NMR spectral assignments of two new sesquiterpene lactone xylosides from Lactuca triangulata
✍ Scribed by Klaudia Michalska; Marek Żylewski; Wanda Kisiel
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 89 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0749-1581
- DOI
- 10.1002/mrc.2323
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✦ Synopsis
Abstract
Two new sesquiterpene lactone xylosides, derivatives of the guaianolides 9α‐hydroxyleucodin and 9α‐hydroxy‐11,13‐dehydroleucodin, were isolated from roots of Lactuca triangulata. Their structures were established on the basis of ^1^H and ^13^C NMR spectra, 2D NMR (HMQC, HMBC, COSY, NOESY) techniques and comparison with the literature data. The compounds represent the first example of sesquiterpene lactone xylosides. Copyright © 2008 John Wiley & Sons, Ltd.
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