Structure du Cu(HPO3H)2
✍ Scribed by Sghyar, M. ;Durand, J. ;Cot, L. ;Rafiq, M.
- Book ID
- 114507169
- Publisher
- International Union of Crystallography
- Year
- 1990
- Tongue
- English
- Weight
- 437 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0108-2701
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📜 SIMILAR VOLUMES
The title compound is prepared by adding aqueous ammonia to a solution of phosphoric acid containing a small amount of iron (III) ions (3%). It crystallizes in the monoclinic system, space group C2/c, a ؍ 16.8450(9) A > , b ؍ 9.6111(1) A > , c ؍ 17.6470(7) A > , and ؍ 90.91(2)°, R ؍ 0.031,
The solution-mediated syntheses and single crystal structures of (N 2 C 6 H 14 ) ' Zn(HPO 4 ) 2 ' H 2 O (I), H 3 N(CH 2 ) 3 NH 3 ' Zn 2 (HPO 4 ) 3 (II), and (N 2 C 6 H 14 ) ' Zn 3 (HPO 4 ) 4 (III) are described. These phases contain vertex-sharing ZnO 4 and HPO 4 tetrahedra, accompanied by doubly pr