Structure at high spin from weak inter-band transitions

Large-Magnitude High-Spin Nuclear Parame

Large-Magnitude High-Spin Nuclear Parameters in a Ti3+Center from X-band EPR Measurements at 10 K

✍ W.C. Tennant; R.F.C. Claridge 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 167 KB

Precise 10 K X-band EPR measurements and subsequent spin-Hamiltonian analysis by direct matrix diagonalization methods are reported for a Ti 3؉ (S ‫؍‬ 1/2) center in tetragonal zircon (zirconium silicate, ZrSiO 4 ). A special, and previously unobserved, feature of the supposedly uniaxial spectrum is