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Structure and Thermal Properties of [Rh(NH3)5Cl](WO4)x(MoO4)1s-x(x= 0, 0.5, 1)

โœ Scribed by S. A. Gromilov; E. A. Shusharina; P. E. Plyusnin; S. P. Khranenko


Publisher
SP MAIK Nauka/Interperiodica
Year
2010
Tongue
English
Weight
139 KB
Volume
51
Category
Article
ISSN
0022-4766

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A 5-layer mixed valence oxide, \(\mathrm{BaVO}_{2.8}\), has been synthesized by reducing \(\mathrm{Ba}_{2} \mathrm{~V}_{2} \mathrm{O}_{7}\) in high purity hydrogen gas at \(1350^{\circ} \mathrm{C}\). \(\mathrm{BaVO}_{2.9}\) has been obtained by room temperature oxidation of \(\mathrm{BaVO}_{2.8}\) i