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Structure and synthesis of gastrolactone

✍ Scribed by Tappey H. Jones; Murray S. Blum


Book ID
104235260
Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
243 KB
Volume
22
Category
Article
ISSN
0040-4039

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✦ Synopsis


Sunmary

The novel cyclopentenoid monoterpene, gastrolactone (4), was synthesized from carvenolide (5), and the synthetic material was found to be identTca1 to the natural product by direct comparison.

This synthesis confirmed structure Twhich had been suggested earlier on the basis of spectral data.

The iridoid monoterpene, chrysomelidial (l), was first identified as a component of the


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