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Structure and structural dynamics of alkylidenesulfur difluorides and alkylidenesulfur difluoride oxides: Experiment versus theory

✍ Scribed by Joseph S. Thrasher


Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
55 KB
Volume
45
Category
Article
ISSN
0022-1139

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Dibenzomethanatoboron difluoride (DBMBF 2 ) interacted with alkylbenzenes from its singlet excited state to form exciplexes ranging from weak polarity up to contact radical ion pairs (CRIP); this exciplex series shows the characteristics in the Marcus ªnormalº region. In cyclohexane these exciplexes