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Structure and Stability of Cd2+ Surface Complexes on Ferric Oxides: 1. Results from EXAFS Spectroscopy

โœ Scribed by Lorenzo Spadini; Alain Manceau; Paul W. Schindler; Laurent Charlet


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
901 KB
Volume
168
Category
Article
ISSN
0021-9797

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Surface Complexation of Hg2+ on Goethite
โœ Clare R Collins; David M Sherman; K.Vala Ragnarsdottir ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 108 KB

EXAFS spectra of Hg 2ุ‰ sorbed on goethite at pH 4.60 has revealed the existence of an inner-sphere complex with an immediate coordination shell of 2 O atoms at 2.04 ร… and a further shell of 1 Fe atom at 3.28 ร…. Using density functional calculations, we determined the optimized geometries of small cl