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Structure and stability, as a function of pH, of borate esters of carbohydrate oximes and related compounds in aqueous media studied by 11B and 13C NMR spectroscopy

โœ Scribed by van Haveren, Jacco; van den Burg, Michael H. B.; Peters, Joop A.; Batelaan, Jan G.; Kieboom, Antonius P. G.; van Bekkum, Herman


Book ID
120056504
Publisher
Royal Society of Chemistry
Year
1991
Tongue
English
Weight
939 KB
Volume
3
Category
Article
ISSN
1472-779X

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The structure and (local) stability cons
โœ Ron van den Berg; Joop A. Peters; Herman van Bekkum ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 833 KB

The formation of borate esters of various mono-and di-saccharides in aqueous solution was studied by "B and 13C NMR spectroscopy. Association constants K(B-L) at a carbohydrate-borate molar ratio of 1: 1, pH 7, and 25ยฐC were determined and compared with literature values obtained from potentiometry.