## Abstract Poly(__N__^δ^‐carbobenzoxy, __N__^δ^‐benzyl‐L‐ornithine) (PCBLO) was prepared by the standard NCA method. PCBLO was converted into poly(__N__^δ^‐benzyl‐L‐ornithine) (PBLO) through decarbobenzoxylation with hydrogen bromide. The monomer __N__^δ^‐benzyl‐L‐ornithine was synthesized by reac
Structure and side-chain interactions in poly(δ-N-carbobenzoxy L-ornithine)
✍ Scribed by Sasaki, Shintaro ;Ban, Hiroshi ;Uematsu, Ichitaro
- Book ID
- 105334793
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1983
- Tongue
- English
- Weight
- 725 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0098-1273
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract The helix–coil transition of poly‐γ‐__N__‐carbobenzoxy‐L‐α,γ‐diaminobutyrate (PCLB) and poly‐δ‐__N__‐carbobenzoxy‐L‐ornithine (PCLO) in chloroform–dichloroacetic acid mixtures was followed by optical rotatory dispersion. PCLB displays a “normal” temperature‐induced transition, but PCLO
## Abstract The helix–coil transitions of poly(__N__^ε^‐methyl, __N__^ε^‐carbobenzoxy‐L‐lysine), poly(__N__^δ^‐methyl, __N__^δ^‐carbobenzoxy‐L‐ornithine), and poly(__N__^δ^‐ethyl, __N__^δ^‐carbobenzoxy‐L‐ornithine) in chloroform–dichloroacetic acid and their corresponding decarbobenzoxylated polype
## Abstract X‐ray diagrams from oriented films and fibers of poly‐__N__^γ^‐carbobenzoxy‐L‐α,γ‐diaminobutyric acid (PCLB) and of poly‐__N__^δ^‐carbobenzoxy‐L‐ornithine (PCLO) have been examined. The conformation in the solid state for both polymers is that of an α‐helix, 18/5 for PCLB and 11/3 for P