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Structure and side-chain interactions in poly(δ-N-carbobenzoxy L-ornithine)

✍ Scribed by Sasaki, Shintaro ;Ban, Hiroshi ;Uematsu, Ichitaro


Book ID
105334793
Publisher
Wiley (John Wiley & Sons)
Year
1983
Tongue
English
Weight
725 KB
Volume
21
Category
Article
ISSN
0098-1273

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## Abstract Poly(__N__^δ^‐carbobenzoxy, __N__^δ^‐benzyl‐L‐ornithine) (PCBLO) was prepared by the standard NCA method. PCBLO was converted into poly(__N__^δ^‐benzyl‐L‐ornithine) (PBLO) through decarbobenzoxylation with hydrogen bromide. The monomer __N__^δ^‐benzyl‐L‐ornithine was synthesized by reac

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## Abstract X‐ray diagrams from oriented films and fibers of poly‐__N__^γ^‐carbobenzoxy‐L‐α,γ‐diaminobutyric acid (PCLB) and of poly‐__N__^δ^‐carbobenzoxy‐L‐ornithine (PCLO) have been examined. The conformation in the solid state for both polymers is that of an α‐helix, 18/5 for PCLB and 11/3 for P