Structure and reactivity of small ring compounds II. Solvolysis studies on some cyclopropylcarbinyl-type derivatives of spirans

✍ Scribed by Takashi Tsuji; Ichiro Moritani; Shinya Nishida; Goro Tadokoro

• Publisher: Elsevier Science
• Year: 1967
• Tongue: French
• Weight: 229 KB
• Volume: 8
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)90668-3

✦ Synopsis

The kinetic studies on the aolvolysia of 4-methyl spiro(2,4]hepte.n-4-yl and 4-methyl spiro[2,5')octan-4-yl e-chlorobenzoates, and their corresponding secondary derivatives were carried out in an aqueous solution of dioxane.

The kinetic results are shown in Table I. The solvolysis of tertiary Spiro esters gave following products and no rearranged product was obtained.