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Structure and reactivity of highly substituted cyclobutyl tosylates

โœ Scribed by Lloyd J. Dolby; Charles L. Wilkins


Book ID
118549813
Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
878 KB
Volume
25
Category
Article
ISSN
0040-4020

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Solvolysis of t-butyl substituted cyclob
โœ Paul v.R. Schleyer; P. LePerchec; Douglas J. Raber ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 194 KB

received in lg for publication g!l Sapfaber 1969) Rigidly held cyclobutyl tosylates show a remarkable dependence of eolvolysis rates on the conformation of the leaving gr0up.a Thus, in both the bicyclo[2.l.l]pentyl and bicyclo[3.1.1]hexyl series, the equatorial isomers (A) are strongly accelerated a