Covers the most advanced computational and experimental methods for studying carbon-centered radical intermediates With its focus on the chemistry of carbon-centered radicals and radical cations, this book helps readers fully exploit the synthetic utility of these intermediates in order to prepare
Structure and reactivity of free radicals trapped in mechanically degraded poly(vinylene carbonate)
✍ Scribed by J Tiňo; J Plaček; P Sláma; E Borsig
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 213 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0032-3861
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The radical trapping technique employing the stable nitroxide 1 as a scavenger has been used to study the reaction of t-butoxyl radicals with diethyl fumarate and with diethyl maleate. The major pathway with both monomers is hydrogen abstraction from the ester alkyl groups by t-butoxyl radicals. The
## Abstract **Summary:** Potentially degradable amphiphilic or hydrophilic copolymeric networks were synthesized directly in water by free radical copolymerization of __α__, __ω__‐poly(1,3‐dioxolane) (PDXL) macromonomers with vinyl monomers such as methyl methacrylate, butyl methacrylate, styrene o